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Structural and spectroscopic insights on the coordination chemistry of the rigid heterotopic chelating ligand 1H-pyrazolo[4,3-h]quinoline (2020)
Journal Article
Goodwin, J. W., Kruger, P. E., & Hawes, C. S. (2020). Structural and spectroscopic insights on the coordination chemistry of the rigid heterotopic chelating ligand 1H-pyrazolo[4,3-h]quinoline. Journal of Coordination Chemistry, 74(1-3), 341-360. https://doi.org/10.1080/00958972.2020.1868041

In this work we report the coordination chemistry of a rigid heterotopic ligand 1H-pyrazolo[4,3-h]quinoline HL1 in copper(II) and zinc(II) complexes for the first time, and examine both the structural properties and solution-phase behaviour of these... Read More about Structural and spectroscopic insights on the coordination chemistry of the rigid heterotopic chelating ligand 1H-pyrazolo[4,3-h]quinoline.

Balancing connectivity with function in silver(i) networks of pyridyltriazole (tzpa) ligands results in the formation of a metallogel (2020)
Journal Article
Hegarty, I. N., Dalton, H. L., Lynes, A. D., Haffner, B., Möbius, M. E., Hawes, C. S., & Gunnlaugsson, T. (2020). Balancing connectivity with function in silver(i) networks of pyridyltriazole (tzpa) ligands results in the formation of a metallogel. Dalton Transactions, 7364-7372. https://doi.org/10.1039/D0DT01421D

A new flexible and divergent 1,2,3-triazol-4-yl-picolinamide (tzpa) ligand 2 and the half-equivalent model ligand 1, both functionalised with pendant 3-pyridyl groups, are reported and their coordination behaviour with silver(i) ions is explored, bot... Read More about Balancing connectivity with function in silver(i) networks of pyridyltriazole (tzpa) ligands results in the formation of a metallogel.

A Series of Manganese(III) Salen Complexes as a Result of Team-Based Inquiry in a Transnational Education Programme. (2020)
Journal Article
Yuan, D., Cai, N., Xu, J., Miao, D., Zhang, S., Woodfine, S. E., …Watkinson, M. (2020). A Series of Manganese(III) Salen Complexes as a Result of Team-Based Inquiry in a Transnational Education Programme. ChemPlusChem, 85(6), 1210 - 1219. https://doi.org/10.1002/cplu.202000337

The development of a team-based approach to research-led transnational practical chemistry teaching is described in which a team of five Chinese students on an articulated transnational degree programme, supported by a team of academic and technical... Read More about A Series of Manganese(III) Salen Complexes as a Result of Team-Based Inquiry in a Transnational Education Programme..

Cyclic Aliphatic Hydrocarbons as Linkers in Metal-Organic Frameworks: New Frontiers for Ligand Design. (2020)
Journal Article
Hawes, C. S. (2020). Cyclic Aliphatic Hydrocarbons as Linkers in Metal-Organic Frameworks: New Frontiers for Ligand Design. ChemPlusChem, 845 - 854. https://doi.org/10.1002/cplu.202000206

In this Minireview we outline the development of cyclic aliphatic moieties as ligands in metal-organic frameworks (MOFs), with a focus on the relationship between ligand design and synthesis and the properties of the subsequent materials. Aliphatic l... Read More about Cyclic Aliphatic Hydrocarbons as Linkers in Metal-Organic Frameworks: New Frontiers for Ligand Design..

Fluorescent supramolecular hierarchical self-assemblies from glycosylated 4-amino- and 4-bromo-1,8-naphthalimides (2020)
Journal Article
Calatrava-Pérez, E., Acherman, S., Stricker, L., McManus, G., Delente, J., Lynes, A. D., …Scanlan, E. M. (in press). Fluorescent supramolecular hierarchical self-assemblies from glycosylated 4-amino- and 4-bromo-1,8-naphthalimides. Organic and Biomolecular Chemistry, 18(18), 3475-3480. https://doi.org/10.1039/d0ob00033g

An investigation into the self-assembly of two 4-amino- and a 4-bromo-1,8-naphthalimide (Nap) based structures (1–3) possessing an appended glycan unit, from protic polar media, is presented. The results demonstrate the formation of complex hierarchi... Read More about Fluorescent supramolecular hierarchical self-assemblies from glycosylated 4-amino- and 4-bromo-1,8-naphthalimides.