Synthesis of glycosyl chlorides using catalytic Appel conditions
(2019)
Journal Article
Pongener, I., Nikitin, K., & McGarrigle, E. M. (in press). Synthesis of glycosyl chlorides using catalytic Appel conditions. Organic and Biomolecular Chemistry, 17(32), 7531-7535. https://doi.org/10.1039/c9ob01544b
The stereoselective synthesis of glycosyl chlorides using catalytic Appel conditions is described. Good yields of α-glycosyl chlorides were obtained using a range of glycosyl hemiacetals, oxalyl chloride and 5 mol% Ph3PO. For 2-deoxysugars treatment... Read More about Synthesis of glycosyl chlorides using catalytic Appel conditions.