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Laboratory exploration of mineral precipitates from Europa’s subsurface ocean

Laboratory exploration of mineral precipitates from Europa’s subsurface ocean Thumbnail


Abstract

The precipitation of hydrated phases from a chondritic-like Na-Mg-Ca-SO4-Cl solution is studied using in situ synchrotron X-ray powder diffraction, under rapid (360
K hour-1, T = 250-80 K, t = 3 hours) and ultra-slow (0.3 K day-1, T= 273-245K, t = 242 days) freezing conditions. The precipitation sequence under slow cooling initially follows the predictions of equilibrium thermodynamics models, however after ~ 50 days at 245 K, the formation of the highly hydrated sulphate phase Na2Mg(SO4)2·16H2O, a relatively recent discovery in the Na2Mg(SO4)2-H2O system, was observed. Rapid freezing, on the other hand, produced an assemblage of multiple phases which formed within a very short timescale (=4 minutes, ?T = 2 K) and, although remaining present throughout, varied in their relative proportions with
decreasing temperature. Mirabilite and meridianiite were the major phases, with pentahydrite, epsomite, hydrohalite, gypsum, bl¨odite, konyaite and loweite also observed. Na2Mg(SO4)2·16H2O was again found to be present and increased in proportion relative to other phases as the temperature decreased. Results are discussed in relation to possible implications for life on Europa and application to other icy ocean worlds.

Acceptance Date Aug 17, 2021
Publication Date Oct 1, 2021
Publicly Available Date Jun 21, 2023
Journal Journal of Applied Crystallography
Print ISSN 0021-8898
Publisher International Union of Crystallography
Pages 1455-1479
DOI https://doi.org/10.1107/S1600576721008554
Keywords Europa, icy moons, low-temperature mineral precipitation, ocean worlds, long-duration studies
Publisher URL https://onlinelibrary.wiley.com/doi/pdf/10.1107/S1600576721008554

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