Metal–organic frameworks as stationary phases for mixed-mode separation applications

Hawes, Chris S.; Nolvachai, Yada; Kulsing, Chadin; Knowles, Gregory P.; Chaffee, Alan L.; Marriott, Philip J.; Batten, Stuart R.; Turner, David R.

Abstract

Polymorphic metal–organic framework (MOF) materials offer a platform for small-scale separation of complex mixtures of polycyclic aromatic hydrocarbons (PAHs) and polar compounds. Retention factors show dependence on both analyte dimensions and polarity, suggesting mixed-mode separation, allowing complete resolution of some analytes from multi-component mixtures.

Citation

Hawes, C. S., Nolvachai, Y., Kulsing, C., Knowles, G. P., Chaffee, A. L., Marriott, P. J., …Turner, D. R. (2014). Metal–organic frameworks as stationary phases for mixed-mode separation applications. Chemical Communications, 50(28), 3735. https://doi.org/10.1039/c4cc00933a

• Journal Article Type: Article
• Publication Date: 2014
• Deposit Date: Jun 16, 2023
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 50
• Issue: 28
• Pages: 3735
• DOI: https://doi.org/10.1039/c4cc00933a
• Keywords: Materials Chemistry; Metals and Alloys; Surfaces, Coatings and Films; General Chemistry; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Catalysis