All Outputs (3)

Engineering entanglement: controlling the formation of polycatenanes and polyrotaxanes using π interactions (2013)
Journal Article
Boer, S. A., Hawes, C. S., & Turner, D. R. (in press). Engineering entanglement: controlling the formation of polycatenanes and polyrotaxanes using π interactions. Chemical Communications, 50(9), 1125-1127. https://doi.org/10.1039/c3cc48802k

A reproducible metallocyclic motif containing amino-acid functionalised aromatic diimides has been employed to demonstrate remarkable control over entanglement topologies. [2]-Catenane and pseudo-rotaxane units give rise to 1D → 2D polycatenation, th... Read More about Engineering entanglement: controlling the formation of polycatenanes and polyrotaxanes using π interactions.

Self-assembly of discrete and polymeric metallosupramolecular architectures from cyclen-derived ligands (2013)
Journal Article
Hawes, C. S., Batten, S. R., & Turner, D. R. (2014). Self-assembly of discrete and polymeric metallosupramolecular architectures from cyclen-derived ligands. CrystEngComm, 16(18), 3737-3748. https://doi.org/10.1039/c3ce42141d

Two divergent ligands 1,4,7,10-tetrakis-(4-cyanobenzyl)-1,4,7,10-tetraazacyclododecane L1 and 1,4,7,10-tetrakis-(4-carboxybenzyl)-1,4,7,10-tetraazacyclododecane dihydrochloride dihydrate H6L2·2Cl·2H2O have been prepared and structurally characterised... Read More about Self-assembly of discrete and polymeric metallosupramolecular architectures from cyclen-derived ligands.

Synthesis, structural and magnetic characterisation of iron(ii/iii), cobalt(ii) and copper(ii) cluster complexes of the polytopic ligand: N-(2-pyridyl)-3-carboxypropanamide (2013)
Journal Article
Russell, M. E., Hawes, C. S., Ferguson, A., Polson, M. I. J., Chilton, N. F., Moubaraki, B., …Kruger, P. E. (2013). Synthesis, structural and magnetic characterisation of iron(ii/iii), cobalt(ii) and copper(ii) cluster complexes of the polytopic ligand: N-(2-pyridyl)-3-carboxypropanamide. Dalton Transactions, 42(37), 13576. https://doi.org/10.1039/c3dt51301g

Herein we describe the synthesis, structural and magnetic characterisation of three transition metal cluster complexes that feature the polytopic ligand N-(2-pyridyl)-3-carboxypropanamide (H2222L): [Fe3IIIFe2II(HL)6(O)(H2O)3][ClO4]5·3MeCN·4H2O, 1, [C... Read More about Synthesis, structural and magnetic characterisation of iron(ii/iii), cobalt(ii) and copper(ii) cluster complexes of the polytopic ligand: N-(2-pyridyl)-3-carboxypropanamide.