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Synthesis, Characterization, and Impact of Water on the Stability of Postmodified Schiff Base Containing Metal–Organic Frameworks (2023)
Journal Article
Radnović, N. D., Hawes, C. S., Kordić, B. B., Bogdanović, M. G., Barta Holló, B., Radanović, M. M., …Rodić, M. V. (in press). Synthesis, Characterization, and Impact of Water on the Stability of Postmodified Schiff Base Containing Metal–Organic Frameworks. Inorganics, 11(11), Article 432. https://doi.org/10.3390/inorganics11110432

In this study, the synthesis of a Schiff base containing metal–organic frameworks (MOFs) of the UiO-67 family has been investigated. MOFs featuring free amine groups were successfully synthesized under mild solvothermal conditions using 2-amino-[1,1′... Read More about Synthesis, Characterization, and Impact of Water on the Stability of Postmodified Schiff Base Containing Metal–Organic Frameworks.

Supporting coordination through hydrogen bonding in lanthanide complexes of 7-azaindole- N -oxide † (2023)
Journal Article
Wood, O. G., Jones, L., & Hawes, C. S. (in press). Supporting coordination through hydrogen bonding in lanthanide complexes of 7-azaindole- N -oxide †. CrystEngComm, 25(45), 6371-6378. https://doi.org/10.1039/d3ce00985h

Ligands capable of simultaneous metal coordination and hydrogen bond donation provide useful structural features to enhance cooperativity and favour specific geometries within the coordination sphere. Here we present the first structurally characteri... Read More about Supporting coordination through hydrogen bonding in lanthanide complexes of 7-azaindole- N -oxide †.

Ligands containing 7-azaindole functionality for inner-sphere hydrogen bonding: structural and photophysical investigations (2023)
Journal Article
Coles, A., Wood, O., & Hawes, C. (2023). Ligands containing 7-azaindole functionality for inner-sphere hydrogen bonding: structural and photophysical investigations. Journal of the Serbian Chemical Society, 88(12), 1223-1236. https://doi.org/10.2298/jsc230623061c

The synthesis, structural analysis and spectroscopic characterisation of three new 7-azaindole ligands is reported, alongside a novel 7-azaindole derived coordination polymer, with the aim of identifying new bridging ligands containing inner-sphere h... Read More about Ligands containing 7-azaindole functionality for inner-sphere hydrogen bonding: structural and photophysical investigations.

Potent antimicrobial effect induced by disruption of chloride homeostasis (2023)
Journal Article
Brennan, L. E., Kumawat, L. K., Piatek, M. E., Kinross, A. J., McNaughton, D. A., Marchetti, L., …Elmes, R. B. (in press). Potent antimicrobial effect induced by disruption of chloride homeostasis. Chem, 9(11), 3138-3158. https://doi.org/10.1016/j.chempr.2023.07.014

Artificial transmembrane ion transporters have proposed applicability to medicinal chemistry, where perturbation of normal cellular homeostasis has already been shown to induce apoptosis in mammalian cells; however, this effect has not been observed... Read More about Potent antimicrobial effect induced by disruption of chloride homeostasis.

Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies (2023)
Journal Article
Hawes, C. S., Chilton, N. F., Moubaraki, B., Knowles, G. P., Chaffee, A. L., Murray, K. S., …Turner, D. R. (in press). Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies. Dalton Transactions, 44(40), 17494-17507. https://doi.org/10.1039/c5dt02323h

The synthesis and structural, magnetic and gas adsorption properties of a series of coordination polymer materials prepared from a new, highly flexible and internally functional tetrakis-carboxybenzyl ligand H4L derived from 1,2-diaminoethane have be... Read More about Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies.

Chemical Diversification of Carbocyclic Fluorinated Pyrimidine Nucleosides: Introducing 2'-Arabino Analogues and Ring Unsaturation (2023)
Journal Article
Benckendorff, C. M. M., Hawes, C. S., Smith, M., & Miller, G. J. (2023). Chemical Diversification of Carbocyclic Fluorinated Pyrimidine Nucleosides: Introducing 2'-Arabino Analogues and Ring Unsaturation. SYNLETT, 35(06), 659-664. https://doi.org/10.1055/a-2079-9310

Analogues of the canonical nucleosides have a longstanding presence and proven capability within medicinal chemistry and drug-discovery research. Herein, we report chemical diversification of carbocyclic pyrimidine nucleosides containing CF2 and CHF... Read More about Chemical Diversification of Carbocyclic Fluorinated Pyrimidine Nucleosides: Introducing 2'-Arabino Analogues and Ring Unsaturation.

Synthesis of α-amino acid derived (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligands and their corresponding luminescent Tb(iii) complexes (2023)
Journal Article
Hegarty, I. N., Hawes, C. S., & Gunnlaugsson, T. (2023). Synthesis of α-amino acid derived (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligands and their corresponding luminescent Tb(iii) complexes. Organic Chemistry Frontiers, 10(8), 1915-1926. https://doi.org/10.1039/D3QO00232B

The synthesis of chiral a-amino acid derived (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligands 4-6 designed by combining the coordination properties of two well-known ligand structures within a single unit is described. The self-assembly formation bet... Read More about Synthesis of α-amino acid derived (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligands and their corresponding luminescent Tb(iii) complexes.