All Outputs (3)

Catalytic and mechanistic studies into the epoxidation of styrenes using manganese complexes of structurally similar polyamine ligands (2013)
Journal Article
Ilyashenko, G., De Faveri, G., Follier, T., Al-Safadi, R., Motevalli, M., & Watkinson, M. (in press). Catalytic and mechanistic studies into the epoxidation of styrenes using manganese complexes of structurally similar polyamine ligands. Organic and Biomolecular Chemistry, 12(7), 1124-1134. https://doi.org/10.1039/c3ob42274g

Two structurally similar polyamine ligands (7 and 8) have been prepared, which differ only by the presence of either a secondary or tertiary nitrogen donor within their N5 donor set. The ligands, in combination with iron and manganese salts, have bee... Read More about Catalytic and mechanistic studies into the epoxidation of styrenes using manganese complexes of structurally similar polyamine ligands.

A synthesis of a 1,1′-desymmetrised ferrocene backbone and its facile one-pot double-“click” functionalisation (2013)
Journal Article
Ilyashenko, G., Al-Safadi, R., Donnan, R., Dubrovka, R., Pancholi, J., Watkinson, M., & Whiting, A. (2013). A synthesis of a 1,1′-desymmetrised ferrocene backbone and its facile one-pot double-“click” functionalisation. RSC advances, 3(38), 17081. https://doi.org/10.1039/c3ra43054e

A one-pot, four-component, copper-catalysed double-“click” functionalisation of a novel 1,1′-desymmetrised ferrocene backbone is reported. Using an array of alkynes and azides, a library of ferrocene compounds was developed, demonstrating the scope o... Read More about A synthesis of a 1,1′-desymmetrised ferrocene backbone and its facile one-pot double-“click” functionalisation.

Initial rate kinetic studies show an unexpected influence of para-substituents on the catalytic behaviour of manganese complexes of TMTACN in the epoxidation of styrenes with H2O2 (2013)
Journal Article
Ilyashenko, G., De Faveri, G., Masoudi, S., Al-Safadi, R., & Watkinson, M. (2013). Initial rate kinetic studies show an unexpected influence of para-substituents on the catalytic behaviour of manganese complexes of TMTACN in the epoxidation of styrenes with H2O2. Organic and Biomolecular Chemistry, 11(12), 1942. https://doi.org/10.1039/c3ob27217f

Investigations into the efficacy of a range of enantiomerically pure BINOL additives in the epoxidation of styrene substrates with a number of manganese catalysts prepared from the ligand 1,4,7-trimethyl-1,4,7-triazacyclononane, TMTACN, using hydroge... Read More about Initial rate kinetic studies show an unexpected influence of para-substituents on the catalytic behaviour of manganese complexes of TMTACN in the epoxidation of styrenes with H2O2.