All Outputs (3)

Preparation of Alkyl Alkynyl Sulfones and Cyclic Vinyl Sulfones from Alkynyl(aryl)iodonium Salts (2016)
Journal Article
Rodríguez, A., & Moran, W. J. (2016). Preparation of Alkyl Alkynyl Sulfones and Cyclic Vinyl Sulfones from Alkynyl(aryl)iodonium Salts. Journal of Organic Chemistry, https://doi.org/10.1021/acs.joc.6b00124

Aqueous DMSO Mediated Conversion of (2-(Arylsulfonyl)vinyl)iodonium Salts to Aldehydes and Vinyl Chlorides (2016)
Journal Article
Zawia, E., & Moran, W. (2016). Aqueous DMSO Mediated Conversion of (2-(Arylsulfonyl)vinyl)iodonium Salts to Aldehydes and Vinyl Chlorides. Molecules, 21(8), Article 1073. https://doi.org/10.3390/molecules21081073

Vinyl(aryl)iodonium salts are useful compounds in organic synthesis but they are under-utilized and their chemistry is under-developed. Herein is described the solvolysis of some vinyl(phenyl)iodonium salts, bearing an arylsulfonyl group, in aqueous... Read More about Aqueous DMSO Mediated Conversion of (2-(Arylsulfonyl)vinyl)iodonium Salts to Aldehydes and Vinyl Chlorides.

Dual oxidation/bromination of alkylbenzenes (2016)
Journal Article
Aborways, M., & Moran, W. (2016). Dual oxidation/bromination of alkylbenzenes. Tetrahedron Letters, https://doi.org/10.1016/j.tetlet.2016.01.062

In the presence of sodium bromide and Oxone, a range of alkylbenzene derivatives are brominated and/or oxidized with up to four C-H bonds being functionalized.