Outputs (12)

One-pot facile synthesis of 4-amino-1,8-naphthalimide derived Tröger's bases via a nucleophilic displacement approach (2017)
Journal Article

We report here a novel one-pot synthetic strategy for the synthesis of a family of N-alkyl-1,8-naphthalimide based Tröger's bases via a nucleophilic substitution reaction of a common ‘precursor’ (or a ‘synthon’) N-aryl-1,8-naphthalimide Tröger's base... Read More about One-pot facile synthesis of 4-amino-1,8-naphthalimide derived Tröger's bases via a nucleophilic displacement approach.

Supramolecular coordination polymers using a close to ‘V-shaped’ fluorescent 4-amino-1,8-naphthalimide Tröger's base scaffold (2017)
Journal Article

A V-shaped 4-amino-1,8-naphthalimide derived dipyridyl ligand comprising the Tröger's base structural motif has been synthesised and subsequently used in the formation of two new supramolecular coordination polymers.

A Schiff-base cross-linked supramolecular polymer containing diiminophenol compartments and its interaction with copper(II) ions (2017)
Journal Article

We report here the preparation of a Schiff-base linked organic polymer 1 based on linkages containing the potent supramolecular aggregator benzene-1,3,5-tricarboxamide, connected through 2,6-diiminophenol metal binding pockets into a cross-linked pol... Read More about A Schiff-base cross-linked supramolecular polymer containing diiminophenol compartments and its interaction with copper(II) ions.

Coordination polymers from a flexible alkyldiamine-derived ligand (2017)
Journal Article

Selectivity differences of coordination compound stationary phases for polyaromatic hydrocarbons and polar analytes in gas and liquid phases (2017)
Journal Article

A precursor solution to the metal–organic framework (MOF), Cd(1,4,7,10-tetrakis(4-carboxybenzyl)-1,4,7,10-tetraazacyclododecane), was aged in a surface-functionalised 250 μm-diameter capillary, to generate a film containing the constituents of the bu... Read More about Selectivity differences of coordination compound stationary phases for polyaromatic hydrocarbons and polar analytes in gas and liquid phases.

Crystal Engineering of 6-Carboxy-4-aryl-2,2′-bipyridine Complexes: Potent Chelators with Intrinsic Intermolecular Affinity (2017)
Journal Article

Herein we report the coordination chemistry and structural properties of two multifunctional terdentate 2,2′-bipyridine derivatives 4- and 3-(4-nitrophenyl)-2,2′-bipyridine-6-carboxylate, L1/L2, respectively. We report eight new coordination complexe... Read More about Crystal Engineering of 6-Carboxy-4-aryl-2,2′-bipyridine Complexes: Potent Chelators with Intrinsic Intermolecular Affinity.

Pyrazolo[4,3-h]quinoline Ligand-Based Iridium(III) Complexes for Electrochemiluminescence (2017)
Journal Article

Electrochemiluminescence (ECL) based on [Ru(bpy)3]2+ systems is widely utilized for immunoassays. In order to extend the promising potential of ECL-based applications, IrIII complexes have recently attracted attention as probes because of their excel... Read More about Pyrazolo[4,3-h]quinoline Ligand-Based Iridium(III) Complexes for Electrochemiluminescence.

A folded [2 x 2] metallo-supramolecular grid from a bis-tridentate (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligand (2017)
Journal Article

A flexible ditopic ligand 1 containing two N,N,O-tridentate (1,2,3-triazol-4-yl)-picolinamide chelating pockets is reported and the formation of multimetallic architectures is explored in the solid and the solution phase. The self-assembled ZnII comp... Read More about A folded [2 x 2] metallo-supramolecular grid from a bis-tridentate (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligand.

Multichannel Luminescent Lanthanide Polymers as Ratiometric Sensors for D2O (2017)
Journal Article

Luminescent sensors for ions and molecules have found numerous applications in areas such as biology, medicine, security, and environmental monitoring. However, designing portable sensors for differentiating similar chemical species, such as D2O in H... Read More about Multichannel Luminescent Lanthanide Polymers as Ratiometric Sensors for D2O.

Benzene-1,3,5-tricarboxamide n-alkyl ester and carboxylic acid derivatives: tuneable structural, morphological and thermal properties (2017)
Journal Article

A family of five benzene-1,3,5-tricarboxamide (BTA) compounds with varied side arm functionality [alkyl: n = 3, 4 and 5 chains; and ester and carboyxic acids] is reported. Investigations into their self-assembly behaviour revealed the extent to which... Read More about Benzene-1,3,5-tricarboxamide n-alkyl ester and carboxylic acid derivatives: tuneable structural, morphological and thermal properties.

Coordination chemistry of N-picolyl-1,8-naphthalimides: colourful low molecular weight metallo-gelators and unique chelation behaviours (2017)
Journal Article

We have prepared a series of N-picolyl-1,8-naphthalimide derivatives and explored their coordination chemistry with d-block metal ions in the solid and solution states, and exploited the structural and chemical properties of these ligands to generat... Read More about Coordination chemistry of N-picolyl-1,8-naphthalimides: colourful low molecular weight metallo-gelators and unique chelation behaviours.

Facile adaptation of 1D Mn(ii) chain motifs to form 3D azo-pyridine-based coordination polymers (2017)
Journal Article

We report the synthesis of a simple 1D Mn-azopyridine-based coordination polymer, poly-[MnII(NO3)2(OH2)2(azopy)2]·2MeCN (1) (azopy = 4,4′-azobis(pyridine)) and its use as a convenient feedstock to afford two 3D coordination polymers, namely: poly-[Mn... Read More about Facile adaptation of 1D Mn(ii) chain motifs to form 3D azo-pyridine-based coordination polymers.