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Low‐Voltage Acidic CO 2 Reduction Enabled by a Diaphragm‐Based Electrolyzer (2024)
Journal Article
Perazio, A., Schreiber, M. W., Creissen, C. E., & Fontecave, M. (in press). Low‐Voltage Acidic CO 2 Reduction Enabled by a Diaphragm‐Based Electrolyzer. ChemElectroChem, 11(9), Article e202400045. https://doi.org/10.1002/celc.202400045

Large‐scale implementation of electrochemical CO2 conversion to value‐added products is currently hampered by high electrolyzer cell voltages, resulting in low energy efficiency and high operating costs. Cell voltages are typically well above 3 V and... Read More about Low‐Voltage Acidic CO 2 Reduction Enabled by a Diaphragm‐Based Electrolyzer.

Multiscale effects in tandem CO 2 electrolysis to C 2+ products (2023)
Journal Article
Cousins, L. S., & Creissen, C. E. (in press). Multiscale effects in tandem CO 2 electrolysis to C 2+ products. Nanoscale, https://doi.org/10.1039/d3nr05547g

CO2 electrolysis is a sustainable technology capable of accelerating global decarbonisation through the production of high-value alternatives to fossil-derived products. CO2 conversion can generate critical multicarbon (C2+) products such as drop-in... Read More about Multiscale effects in tandem CO 2 electrolysis to C 2+ products.

Acidic Electroreduction of CO<sub>2</sub> to Multi-Carbon Products with CO<sub>2</sub> Recovery and Recycling from Carbonate (2023)
Journal Article
Perazio, A., Creissen, C. E., Rivera de la Cruz, J. G., Schreiber, M. W., & Fontecave, M. (in press). Acidic Electroreduction of CO2 to Multi-Carbon Products with CO2 Recovery and Recycling from Carbonate. ACS Energy Letters, 8(7), 2979-2985. https://doi.org/10.1021/acsenergylett.3c00901

Gas-fed flow cells can facilitate high-rate electrochemical CO2 reduction (CO2R). However, under alkaline and neutral conditions, CO2 is lost through reaction with hydroxide ions to form (bi)carbonate. In acidic solutions, although (bi)carbonate is s... Read More about Acidic Electroreduction of CO<sub>2</sub> to Multi-Carbon Products with CO<sub>2</sub> Recovery and Recycling from Carbonate.

Molecular Catalysts Immobilised on Photocathodes for Solar Fuel Generation (2023)
Book Chapter
Creissen, C. E. (2023). Molecular Catalysts Immobilised on Photocathodes for Solar Fuel Generation. In Recent Developments in Functional Materials for Artificial Photosynthesis (120-156). Royal Society of Chemistry. https://doi.org/10.1039/9781839167768-00120

The solar-driven transformation of water and carbon dioxide into valuable chemicals offers a sustainable route to bypass the use of fossil fuels. This can be achieved using molecular catalysts immobilised on semiconductor surfaces. Hybrid photocathod... Read More about Molecular Catalysts Immobilised on Photocathodes for Solar Fuel Generation.

Molecular Inhibition for Selective CO2 Conversion. (2022)
Journal Article
Creissen, C., Rivera de la Cruz, J., Karapinar, D., Taverna, D., Schreiber, M., & Fontecave, M. (2022). Molecular Inhibition for Selective CO2 Conversion. Angewandte Chemie International Edition, e202206279 - ?. https://doi.org/10.1002/anie.202206279

Electrochemical CO2 reduction presents a sustainable route to the production of chemicals and fuels. Achieving a narrow product distribution with heterogeneous Cu catalysts is challenging and conventional material modifications offer limited control... Read More about Molecular Inhibition for Selective CO2 Conversion..

Molecular Inhibition for Selective CO 2 Conversion (2022)
Journal Article
Creissen, C. E., Rivera de la Cruz, J. G., Karapinar, D., Taverna, D., Schreiber, M. W., & Fontecave, M. (2022). Molecular Inhibition for Selective CO 2 Conversion. Angewandte Chemie, 134(32), https://doi.org/10.1002/ange.202206279

Electrochemical CO2 reduction presents a sustainable route to the production of chemicals and fuels. Achieving a narrow product distribution with heterogeneous Cu catalysts is challenging and conventional material modifications offer limited control... Read More about Molecular Inhibition for Selective CO 2 Conversion.

From Nickel Foam to Highly Active NiFe-based Oxygen Evolution Catalysts (2022)
Journal Article
Peugeot, A., Creissen, C. E., Schreiber, M. W., & Fontecave, M. (2022). From Nickel Foam to Highly Active NiFe-based Oxygen Evolution Catalysts. ChemElectroChem, 9(6), Article ARTN e202200148. https://doi.org/10.1002/celc.202200148

A key challenge for the large-scale application of the oxygen evolution reaction (OER) is the synthesis of active, cheap and robust catalysts. Here, a straightforward procedure to form novel porous and highly active multimetallic oxygen evolution cat... Read More about From Nickel Foam to Highly Active NiFe-based Oxygen Evolution Catalysts.

Molecular Inhibition for Selective CO2 Conversion (2022)
Journal Article
Schreiber, M., Fontecave, M., Creissen, C., Guillermo Rivera de la Cruz, J., Karapinar, D., & Taverna, D. (2022). Molecular Inhibition for Selective CO2 Conversion. ChemRxiv, https://doi.org/10.26434/chemrxiv-2022-63b91

Electrochemical CO2 reduction presents a sustainable route to the production of chemicals and fuels. Achieving a narrow product distribution with copper catalysts is challenging and conventional material modifications offer limited control over selec... Read More about Molecular Inhibition for Selective CO2 Conversion.

Solar-Driven Electrochemical CO(2)Reduction with Heterogeneous Catalysts (2021)
Journal Article
Creissen, C. E., & Fontecave, M. (2021). Solar-Driven Electrochemical CO(2)Reduction with Heterogeneous Catalysts. Laser physics review, 11(43), Article ARTN 2002652. https://doi.org/10.1002/aenm.202002652

The simultaneous mitigation of CO2 emissions and direct generation of value-added chemicals has motivated research in solar-driven electrochemical CO2 reduction. Here, devices incorporating heterogeneous catalysts that operate under bias-free aqueous... Read More about Solar-Driven Electrochemical CO(2)Reduction with Heterogeneous Catalysts.