Gavin Miller g.j.miller@keele.ac.uk
6R/S-deutero-a-d-mannopyranoside 1-phosphate
Miller, Gavin; Ahmadipour, Sanaz
Authors
Sanaz Ahmadipour
Abstract
6R/S-deutero-a-d-mannopyranoside 1-phosphate was synthesised from a C6 aldehydic mannose thioglycoside donor in four steps. Using NaBD4 as the reductant, isotopic enrichment at C6 was achieved and the resultant C6-deuterated material was converted through to the glycosyl 1-phosphate using a protection/glycosylation/deprotection sequence. The product was fully characterised by 1H, 13C, 31P and 2D NMR, alongside MS analysis.
Citation
Miller, G., & Ahmadipour, S. (2019). 6R/S-deutero-a-d-mannopyranoside 1-phosphate. Molbank, 2019(3), Article M1068. https://doi.org/10.3390/M1068
Journal Article Type | Article |
---|---|
Acceptance Date | Jun 24, 2019 |
Publication Date | Jun 27, 2019 |
Journal | Molbank |
Publisher | MDPI |
Peer Reviewed | Peer Reviewed |
Volume | 2019 |
Issue | 3 |
Article Number | M1068 |
DOI | https://doi.org/10.3390/M1068 |
Keywords | mannose; glycosyl-phosphate; deuterium; isotope; NMR |
Publisher URL | https://doi.org/10.3390/M1068 |
Files
Manuscript_Miller_Revised.docx
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Document
Publisher Licence URL
https://creativecommons.org/licenses/by/4.0/
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