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Iodoarene-catalyzed cyclizations of N-propargylamides and β-amidoketones: synthesis of 2-oxazolines

Kamouka, Somaia; Moran, Wesley J.

Authors

Somaia Kamouka



Abstract

Two complementary iodoarene-catalyzed methods for the preparation of 2-oxazolines are presented. The first involves the cyclization of N-propargylamides and the second involves the cyclization of β-amidoketones. These are proposed to proceed through different mechanisms and have different substrate scopes.

Journal Article Type Article
Acceptance Date Aug 17, 2017
Online Publication Date Aug 31, 2017
Publication Date Aug 31, 2017
Deposit Date Mar 11, 2024
Journal Beilstein Journal of Organic Chemistry
Print ISSN 1860-5397
Publisher Beilstein-Institut
Peer Reviewed Peer Reviewed
Volume 13
Pages 1823–1827
DOI https://doi.org/10.3762/bjoc.13.177
Keywords amides; catalysis; cyclization; hypervalent iodine; isoxazolines