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Gas-liquid flow hydrogenation of nitroarenes: Efficient access to a pharmaceutically relevant pyrrolobenzo[1,4]diazepine scaffold (2018)
Journal Article
Dimitriou, E., Jones, R., Pritchard, R., Miller, G., & O'Brien, M. (2018). Gas-liquid flow hydrogenation of nitroarenes: Efficient access to a pharmaceutically relevant pyrrolobenzo[1,4]diazepine scaffold. Tetrahedron, 74(47), 6795-6803. https://doi.org/10.1016/j.tet.2018.09.025

Using a Tube-in-Tube device based on the amorphous Teflon AF-2400 fluoropolymer, a series of nitroarenes was hydrogenated to afford the corresponding aniline compounds. The system was then applied to the construction of a pyrrolobenzo[1,4]diazapene s... Read More about Gas-liquid flow hydrogenation of nitroarenes: Efficient access to a pharmaceutically relevant pyrrolobenzo[1,4]diazepine scaffold.

Negative 2D thermal expansion in the halogen bonded acetone bromine complex (2018)
Journal Article
Jones. (2018). Negative 2D thermal expansion in the halogen bonded acetone bromine complex. CrystEngComm, 3246-3250. https://doi.org/10.1039/c7ce01923h

The crystal structure of the complex formed between acetone and bromine has been determined between 14 K and 200 K. The structure exhibits negative 2D thermal expansion at low temperature and colossal thermal expansion in the perpendicular dimension.... Read More about Negative 2D thermal expansion in the halogen bonded acetone bromine complex.