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A synthesis of C-glycosidic multivalent mannosides suitable for divergent functionalized conjugation

Miller

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Abstract

Divergent synthesis of two novel C-glycosidic multivalent mannosides derived from a common trivalent C-mannosyl carboxylate-terminated intermediate is described. This illustrates synthesis of multivalent C-glycosidic architectures bearing variable extended functionalized tethers. One such tether incorporates an embedded fluorescent unit providing a C-mannosyl multivalent epitope offering potential applications through further conjugation or immobilization.

Citation

Miller. (2011). A synthesis of C-glycosidic multivalent mannosides suitable for divergent functionalized conjugation. Tetrahedron Letters, 3216 - 3218. https://doi.org/10.1016/j.tetlet.2011.04.047

Acceptance Date Apr 11, 2011
Publication Date Apr 18, 2011
Journal Tetrahedron Letters
Print ISSN 0040-4039
Publisher Elsevier
Pages 3216 - 3218
DOI https://doi.org/10.1016/j.tetlet.2011.04.047
Keywords C-Glycosides, Multivalency, Carbohydrates, Glycobiology, Glycoconjugation
Publisher URL https://doi.org/10.1016/j.tetlet.2011.04.047

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