Dawn E. Barry
A folded [2 x 2] metallo-supramolecular grid from a bis-tridentate (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligand
Barry, Dawn E.; Hawes, Chris S.; Byrne, Joseph P.; la Cour Poulsen, Bjørn; Ruether, Manuel; O'Brien, John E.; Gunnlaugsson, Thorfinnur
Authors
Chris Hawes c.s.hawes@keele.ac.uk
Joseph P. Byrne
Bjørn la Cour Poulsen
Manuel Ruether
John E. O'Brien
Thorfinnur Gunnlaugsson
Abstract
A flexible ditopic ligand 1 containing two N,N,O-tridentate (1,2,3-triazol-4-yl)-picolinamide chelating pockets is reported and the formation of multimetallic architectures is explored in the solid and the solution phase. The self-assembled ZnII complex [Zn4(1)4](ClO4)8 exhibited a folded [2 × 2] square grid supramolecular architecture that selectively assembled in MeCN solution as shown using various spectroscopic techniques. The closely related FeII complex shows equivalent behaviour in the solid state, while a discrete dinuclear species [Cu2(NO3)41]·5MeCN was the sole product observed in the solid state from the reaction between 1 and CuII under similar conditions.
Citation
Barry, D. E., Hawes, C. S., Byrne, J. P., la Cour Poulsen, B., Ruether, M., O'Brien, J. E., & Gunnlaugsson, T. (2017). A folded [2 x 2] metallo-supramolecular grid from a bis-tridentate (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligand. Dalton Transactions, 6464 -6472. https://doi.org/10.1039/C7DT01533J
Acceptance Date | Apr 27, 2017 |
---|---|
Publication Date | May 21, 2017 |
Journal | Dalton Transactions |
Print ISSN | 1477-9226 |
Publisher | Royal Society of Chemistry |
Pages | 6464 -6472 |
DOI | https://doi.org/10.1039/C7DT01533J |
Publisher URL | http://dx.doi.org/10.1039/C7DT01533J |
Files
Manuscript_No Markup.docx
(4.3 Mb)
Document
Publisher Licence URL
https://creativecommons.org/licenses/by-nc/4.0/
You might also like
Downloadable Citations
About Keele Repository
Administrator e-mail: research.openaccess@keele.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2025
Advanced Search