H-K Luo
Novel properties and potential applications of functional ligand-modified polyoxotitanate cages
Luo, H-K; Li, N; Matthews, P; Wright, DS
Abstract
Functional ligand-modified polyoxotitanate (L-POT) cages of the general type [TixOy(OR)z(L)m] (OR = alkoxide, L = functional ligand) can be regarded as molecular fragments of surface-sensitized solid-state TiO2, and are of value as models for studying the interfacial charge and energy transfer between the bound functional ligands and a bulk semiconductor surface. These L-POTs have also had a marked impact in many other research fields, such as single-source precursors for TiO2 deposition, inorganic–organic hybrid material construction, photocatalysis, photoluminescence, asymmetric catalysis and gas adsorption. Their atomically well-defined structures provide the basis for the understanding of structure/property relationships and ultimately for the rational design of new cages targeting specific uses. This highlight focuses on recent advances in L-POTs research, with emphasis on their novel properties and potential applications.
Citation
Luo, H., Li, N., Matthews, P., & Wright, D. (2016). Novel properties and potential applications of functional ligand-modified polyoxotitanate cages. Chemical Communications, 11180-11190. https://doi.org/10.1039/C6CC03788G
Acceptance Date | Jun 14, 2016 |
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Publication Date | Jun 14, 2016 |
Journal | Chemical Communications |
Print ISSN | 1359-7345 |
Publisher | Royal Society of Chemistry |
Pages | 11180-11190 |
DOI | https://doi.org/10.1039/C6CC03788G |
Publisher URL | https://doi.org/10.1039/c6cc03788g |
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