Recent advances in the catalytic oxidation of alkene and alkane substrates using immobilized manganese complexes with nitrogen containing ligands

Nodzewska, Aneta; Wadolowska, Agnieszka; Watkinson, Mike

Abstract

In recent years, many supported manganese catalysts for the oxidative transformations of hydrocarbons by various terminal oxidants have been designed and tested. A vast range of inorganic (e.g. silica, carbon, zeolites), organic (e.g. polymers, dendrimers), and hybrid (e.g. polymeric phosphates, metal-organic frameworks) materials have been chosen to immobilise catalysts using various anchoring and embedding methods including covalent bonding, axial coordination and non-covalent interactions. This review provides a comprehensive overview of the applications of heterogenised manganese complexes with different nitrogen containing ligands, including porphyrins, salens and amines immobilized on inorganic or/and organic supports in the catalytic oxidation of alkanes and alkenes.

Citation

Nodzewska, A., Wadolowska, A., & Watkinson, M. (2019). Recent advances in the catalytic oxidation of alkene and alkane substrates using immobilized manganese complexes with nitrogen containing ligands. Coordination Chemistry Reviews, 382, 181-216. https://doi.org/10.1016/j.ccr.2018.12.004

• Journal Article Type: Article
• Acceptance Date: Dec 11, 2018
• Online Publication Date: Jan 4, 2019
• Publication Date: Mar 1, 2019
• Publicly Available Date: May 26, 2023
• Journal: Coordination Chemistry Reviews
• Print ISSN: 0010-8545
• Publisher: Elsevier
• Volume: 382
• Pages: 181-216
• DOI: https://doi.org/10.1016/j.ccr.2018.12.004
• Keywords: alkene; alkane; manganese; ligands
• Publisher URL: https://doi.org/10.1016/j.ccr.2018.12.004